Consider the chemical reaction below:

[tex]\[ Zn (s) + 2 H^{+} (aq) \longrightarrow Zn^{2+} (aq) + H_2 (g) \][/tex]

Which half-reaction correctly represents the reduction for this equation?

A. [tex]\( Zn (s) \longrightarrow Zn^{2+} (aq) + 2 e^{-} \)[/tex]

B. [tex]\( 2 H^{+} (aq) + 2 e^{-} \longrightarrow H_2 (g) \)[/tex]

C. [tex]\( Zn (s) \longrightarrow Zn^{2+} (aq) + e^{-} \)[/tex]

D. [tex]\( 2 H^{+} (aq) + e^{-} \longrightarrow H_2 (g) \)[/tex]



Answer :

To determine which of the half-reactions represents reduction in the given chemical equation, we need to identify which of the processes involve a gain of electrons.

Reduction is the process of gaining electrons, whereas oxidation is the process of losing electrons.

Given chemical reaction:
[tex]$ Zn (s) + 2 H^{+}(aq) \rightarrow Zn^{2+}(aq) + H_2(g) $[/tex]
Let's look at the provided half-reactions:

1. [tex]\( \text{Zn} (s) \rightarrow \text{Zn}^{2+}(aq) + 2 e^{-} \)[/tex]

2. [tex]\( 2 H^{+}(aq) + 2 e^{-} \rightarrow H_2(g) \)[/tex]

3. [tex]\( \text{Zn} (s) \rightarrow \text{Zn}^{2+}(aq) + e^{-} \)[/tex]

4. [tex]\( 2 H^{+}(aq) + e^{-} \rightarrow H_2(g) \)[/tex]

To identify the reduction half-reaction, we must check which reaction involves the gain of electrons.

1. In the reaction [tex]\( \text{Zn} (s) \rightarrow \text{Zn}^{2+}(aq) + 2 e^{-} \)[/tex], zinc is losing electrons (oxidation).

2. In the reaction [tex]\( 2 H^{+}(aq) + 2 e^{-} \rightarrow H_2(g) \)[/tex], the hydrogen ions ([tex]\(H^{+}\)[/tex]) are gaining electrons to form hydrogen gas (reduction).

3. In the reaction [tex]\( \text{Zn} (s) \rightarrow \text{Zn}^{2+}(aq) + e^{-} \)[/tex], zinc is again losing electrons (oxidation).

4. In the reaction [tex]\( 2 H^{+}(aq) + e^{-} \rightarrow H_2(g) \)[/tex], once again, hydrogen ions ([tex]\(H^{+}\)[/tex]) are gaining electrons (but the stoichiometry doesn't match the given reaction).

Among these, the correct half-reaction that represents a reduction process (gain of electrons) and matches the stoichiometry of the given equation is:

[tex]\( 2 H^{+}(aq) + 2 e^{-} \rightarrow H_2(g) \)[/tex]

Therefore, the correct half-reaction representing reduction is:
[tex]\( 2 H^{+}(aq) + 2 e^{-} \rightarrow H_2(g) \)[/tex]

Hence, the second half-reaction correctly represents reduction for this equation.

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